Thermal decomposition reactions as tool for the synthesis of new metal thiocyanate diazine coordination polymers with cooperative magnetic phenomena.

@article{Wriedt2009ThermalDR,
  title={Thermal decomposition reactions as tool for the synthesis of new metal thiocyanate diazine coordination polymers with cooperative magnetic phenomena.},
  author={Mario Wriedt and Sina Sellmer and C. N{\"a}ther},
  journal={Inorganic chemistry},
  year={2009},
  volume={48 14},
  pages={
          6896-903
        }
}
Reaction of nickel thiocyanate with pyrimidine at room temperature leads to the formation of the new ligand-rich 1:2 (1:2 = ratio between metal and ligand) compound [Ni(NCS)(2)(pyrimidine)(2)](n) (2) which is isotypic to [Co(NCS)(2)(pyrimidine)(2)](n) (1) reported recently. In the crystal structure, the Ni(2+) ions are coordinated by four N atoms of pyrimidine ligands, which connect the metal centers into layers, and two N atoms of terminal bonded thiocyanato anions within slightly distorted… Expand
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