Thermal decomposition modes for four-coordinate ruthenium phosphonium alkylidene olefin metathesis catalysts.


The four-coordinate ruthenium phosphonium alkylidenes 1-Cy and 1-iPr, differing in the substituent on the phosphorus center, were observed to decompose thermally in the presence of 1,1-dichloroethylene to produce [H(3)CPR(3)][Cl]. The major ruthenium-containing product was a trichloro-bridged ruthenium dimer that incorporates the elements of the 1,1… (More)
DOI: 10.1002/chem.200801584


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