Theory and Experiment on the Measurement of Kinetic Rate Constants for Surfactant Exchange at an Air/Water Interface.

@article{Pan1998TheoryAE,
  title={Theory and Experiment on the Measurement of Kinetic Rate Constants for Surfactant Exchange at an Air/Water Interface.},
  author={Pan and F Green and Maldarelli},
  journal={Journal of colloid and interface science},
  year={1998},
  volume={205 2},
  pages={213-230}
}
The paper focuses on the measurement of the rate constants for the kinetic steps of adsorption and desorption of surfactant between an air/water surface and the aqueous bulk sublayer adjacent to the surface. Kinetic constants are determined in nonequilibrium experiments in which either a clean surface is contacted with a bulk solution and surfactant diffuses toward and adsorbs onto the interface, or the area of an established monolayer in equilibrium with an underlying solution is changed, and… CONTINUE READING

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