Theoretical study of the thermal decomposition of dimethyl disulfide.

@article{Vandeputte2010TheoreticalSO,
  title={Theoretical study of the thermal decomposition of dimethyl disulfide.},
  author={A{\"a}ron G. Vandeputte and M. F. Reyniers and Guy B. Marin},
  journal={The journal of physical chemistry. A},
  year={2010},
  volume={114 39},
  pages={10531-49}
}
Despite its use in a wide variety of industrially important thermochemical processes, little is known about the thermal decomposition mechanism of dimethyl disulfide (DMDS). To obtain more insight, the radical decomposition mechanism of DMDS is studied theoretically and a kinetic model is developed accounting for the formation of all the decomposition products observed in the experimental studies available in literature. Thermochemical data and rate coefficients are obtained using the high… CONTINUE READING

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