Theoretical spectroscopic characterization at low temperatures of S-methyl thioformate and O-methyl thioformate.

@article{Senent2014TheoreticalSC,
  title={Theoretical spectroscopic characterization at low temperatures of S-methyl thioformate and O-methyl thioformate.},
  author={Maria Luisa Senent and Cristina Puzzarini and Majdi Hochlaf and R. Dom{\'i}nguez-G{\'o}mez and Miguel Carvajal},
  journal={The Journal of chemical physics},
  year={2014},
  volume={141 10},
  pages={104303}
}
Highly correlated ab initio methods are employed to determine spectroscopic properties at low temperatures of two S-analogs of methyl formate: S-methyl thioformate CH3-S-CHO (MSCHO) and O-methyl thioformate CH3-O-CHS (MOCHS). Both species are detectable and they are expected to play an important role in Astrochemistry. Molecular properties are compared with… CONTINUE READING