The trans effect in square-planar platinum(II) complexes - A density functional study

@article{Chval2008TheTE,
  title={The trans effect in square-planar platinum(II) complexes - A density functional study},
  author={Zdenek Chval and Miroslav Sip and Jaroslav V. Burda},
  journal={Journal of computational chemistry},
  year={2008},
  volume={29 14},
  pages={2370-81}
}
The mechanism of substitution water exchange reactions in square planar trans-Pt[(NH(3))(2)T(H(2)O)](n+) complexes is studied (T = H(2)O, NH(3), OH(-), F(-), Cl(-), Br(-), H(2)S, CH(3)S(-), SCN(-), CN(-), PH(3), CO, CH(3)(-), H(-), C(2)H(4)). The trans effect is explained in terms of sigma-donation and pi-back-donation whose relative strengths are quantified by the changes of electron occupations of 5d platinum atomic orbitals. The sigma-donation strength is linearly correlated with the Pt-H(2… CONTINUE READING

Citations

Publications citing this paper.

References

Publications referenced by this paper.
Showing 1-5 of 5 references

, 250 , 2261 ; ( b )

M. Melnik, C. E. Holloway
Coord Chem Rev • 2006

Gaussian 03, Revision C

J M., G. W. Trucks, +35 authors J. Jaramillo
Gom- perts, • 2003
View 1 Excerpt

, 22 , 901 ; ( d )

R. Wysokinski, D. Michalska
J Comput Chem • 2001

Pract (CERP; special ‘‘Structural Concepts’

F. Weinhold, C. R. Chem Ed Res Landis
issue) 2001, • 2001
View 1 Excerpt

, 37 , 785 ; ( d )

C. T. Lee, W. T. Yang, R. G. Parr
Phys Rev B • 1988

Similar Papers

Loading similar papers…