The thermodynamics of the elusive HO3 radical.


The role of HO3 as a temporary reservoir of atmospheric OH radicals remains an open question largely because of the considerable uncertainty in the value of the dissociation energy of the HO-O2 bond (D0) or, equivalently, the standard enthalpy of formation of HO3 (Delta(f)H;{\overline{);\circ }}$$). Using a supersonic flow apparatus, we have observed by… (More)
DOI: 10.1126/science.1184459


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@article{Picard2010TheTO, title={The thermodynamics of the elusive HO3 radical.}, author={S{\'e}bastien D Le Picard and Meryem Tizniti and Andr{\'e} Canosa and Ian R. Sims and Ian M. Smith}, journal={Science}, year={2010}, volume={328 5983}, pages={1258-62} }