The self-organized phase of bulk P x Se 1 ? x glasses

@inproceedings{Georgiev2003TheSP,
  title={The self-organized phase of bulk P x Se 1 ? x glasses},
  author={Daniel Georgiev Georgiev and Punit Boolchand and Hellmut Eckert and Matthieu Micoulaut and Koblar A. Jackson},
  year={2003}
}
Modulated Scanning Calorimetry shows the non-reversing heat flow near Tg to display a sharply defined global minimum in the 0.28 < x < 0.40 range, identified with the self-organized phase (SOP) of titled glasses. 31P NMR, Raman scattering and constraint counting algorithms suggest this phase to consist of two distinct global morphologies; a Se-rich backbone that has a dimensionality 2 < d < 3, and P-rich ribbons that have d 1. The ribbons dominate the physical behavior of stressed rigid (0.40… CONTINUE READING

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