The reaction of iron chlorides with some aliphatic primary amines

  title={The reaction of iron chlorides with some aliphatic primary amines},
  author={W. R. McGregor and F. J. Swinbourne},
  journal={Journal of Inorganic and Nuclear Chemistry},
Abstract The reaction at room temperature of iron (III) chloride with excess of several primary amines has been studied. With each primary amine (NH2R, R  Me, Et, Prn and Bun) reduction to iron (II) takes place and compounds of formula FeCl2, 2RNH2 are obtained. Compounds with the same formula are produced by direct reaction of iron (II) chloride with the appropriate amine. Structures for the compounds are suggested on the basis of magnetic and spectroscopic studies. 
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