The most reactive iron and manganese complexes with N-pentadentate ligands for dioxygen activation—synthesis, characteristics, applications

@article{RydelCiszek2021TheMR,
  title={The most reactive iron and manganese complexes with N-pentadentate ligands for dioxygen activation—synthesis, characteristics, applications},
  author={Katarzyna Rydel-Ciszek},
  journal={Reaction Kinetics, Mechanisms and Catalysis},
  year={2021},
  volume={133},
  pages={579 - 600}
}
The iron and manganese complexes that activate oxygen atom play multiple role in technologically relevant reactions as well as in biological transformations, in which exist in different redox states. Among them, high-valent oxo intermediate seems to be the most important one. Iron, and/or manganese-based processes have found application in many areas, starting from catalysis and sustainable technologies, through DNA oxidative cleavage, to new substances useful in chemotherapeutic drugs. This… 

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