The molecular and supramolecular aspects in mononuclear manganese(iii) Schiff-base spin crossover complexes.

@article{Wang2017TheMA,
  title={The molecular and supramolecular aspects in mononuclear manganese(iii) Schiff-base spin crossover complexes.},
  author={Shi Wang and Ya-juan Li and Fei-Fei Ju and Wu-Tan Xu and Koichi Kagesawa and Yong-Hua Li and Masahiro Yamashita and Wei Huang},
  journal={Dalton transactions},
  year={2017},
  volume={46 33},
  pages={11063-11077}
}
Manganese(iii) hexadentate Schiff base complexes ([Mn(sal-N-1,5,8,12)]Y·S, Y = AsF6 (1); Y = SbF6 (2); Y = NO3, S = C2H5OH (3) and Y = Cl (4)) have been investigated to determine the impact of anion effects, intramolecular ligand distortions, and intermolecular supramolecular structures on the spin crossover (SCO) behavior. The crystal structure of [Mn(sal-N-1,5,8,12)]PF6, a complex known to exhibit an abrupt SCO behavior with an 8 K hysteresis window, reveals that this complex has a… CONTINUE READING