The ionothermal synthesis, structure, and magnetism-structure relationship of two biphenyl tetracarboxylic acid-based metal-organic frameworks.

@article{Chen2014TheIS,
  title={The ionothermal synthesis, structure, and magnetism-structure relationship of two biphenyl tetracarboxylic acid-based metal-organic frameworks.},
  author={Wen-xian Chen and Li Tan and Qiu-ping Liu and Gen-Rong Qiang and Gui-Lin Zhuang},
  journal={Dalton transactions},
  year={2014},
  volume={43 43},
  pages={16515-21}
}
Two new metal-organic frameworks (1-2) were ionothermally obtained by the reaction of a biphenyltetracarboxylic sodium (Na4BPTC) ligand and M(OOCCH3)2 (M = Co(1) and Mn(2)). Crystal structure analysis reveals that 1 is a Co3Na6 unit-based three dimensional heterometallic MOF, while 2 exhibits a {Mn(COO)n} chain-based three-dimensional framework. Furthermore… CONTINUE READING