Corpus ID: 101620669

The investigation on the band structures of the anions of Mo2S4(i-mnt)(2)(Et4N)(2) and (Et4N)(3)K[Mo2S4(i-mnt)(2)](2)[i-mnt=S2C(CN)(2-)] complexes

@article{Cai1998TheIO,
  title={The investigation on the band structures of the anions of Mo2S4(i-mnt)(2)(Et4N)(2) and (Et4N)(3)K[Mo2S4(i-mnt)(2)](2)[i-mnt=S2C(CN)(2-)] complexes},
  author={S. Cai and Z. Chen and 陈忠 and F. Sun and Xc Gao and S. Lu},
  journal={Acta Chimica Sinica},
  year={1998}
}
The anions of complexes Mo2S4(i - mnt)2(Et4N)2 and (Et4N)3K[Mo2S4(i - mnt)2]2[i - mnt = S2C(CN)2-] form special chains in the crystals. In this paper, their band structures have been studied by using the tight - binding energy band method within the extended Huckel scheme. It is found that there exist weak interactions between adjacent anions and this kind of interactions is the basis for the formation of the chain. The chain structures are correlated with the semiconducting properties of the… Expand