The influence of π-π-stacking on the light-harvesting properties of perylene bisimide antennas that are covalently linked to a [60]fullerene.

Abstract

A flexible organic triad consisting of two perylene bisimide antennas covalently linked to a [60]fullerene by flexible spacers has been synthesized and studied by electrochemistry, steady-state and time-resolved spectroscopy. We found that π-π-stacking of the two antenna subunits has considerable impact on the photophysics of the system and leads to a… (More)
DOI: 10.1039/c0cp01200a

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