The hydrogen bond properties of water from 273 K to 573 K; equations for the prediction of gas-water partition coefficients.

An equation due to Plyasunov and Shock for the calculation of gas to water partition coefficients, as log K(w), at high temperature requires knowledge of experimental values of log K, ΔH the standard enthalpy of hydration at 298 K, ΔCp the heat capacity of hydration at 298 K and b' that is a constant that refers to the variation of ΔCp(w) with temperature… CONTINUE READING