The gas-phase basicity and proton affinity of 7-methyl-1,3,5-cycloheptatriene as determined by the thermokinetic method.

@article{Mormann2007TheGB,
  title={The gas-phase basicity and proton affinity of 7-methyl-1,3,5-cycloheptatriene as determined by the thermokinetic method.},
  author={Michael Mormann and Dietmar Kuck},
  journal={Journal of mass spectrometry : JMS},
  year={2007},
  volume={42 2},
  pages={
          263-5
        }
}
  • M. Mormann, D. Kuck
  • Published 2007
  • Chemistry, Medicine
  • Journal of mass spectrometry : JMS
4 Citations
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From Fragmentation to Construction--from Void to Massive: Fascination with Organic Mass Spectrometry and the Synthesis of Novel Three-Dimensional Polycyclic Aromatic Hydrocarbons.
  • D. Kuck
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TLDR
It is shown how unexpected reactivity of related ions in solution can lead to the construction of novel and, in part, unique three-dimensional polycyclic structures that may contribute to future research in material science. Expand
Energetics and Reaction Mechanisms for the Competitive Losses of H2, CH4 and C2H4 from Protonated Methylbenzenes—Implications to the Methanol-to-Hydrocarbons (MTH) Process
We report the unimolecular decomposition following collisional activation of protonated mono-, di- and trimethylbenzenes as a function of collision energy. The resulting energy-resolved mass spectraExpand
Composite C- and H-scrambling and fragmentation of long-lived protonated 6-methylfulvene and 6,6-dimethylfulvene—alternative entry to the gas-phase chemistry of gaseous toluenium (C7H9+) and xylenium (C8H11+) ions
Abstract The fragmentation of metastable 6-methylfulvenium and 6,6-dimethylfulvenium ions, generated by gas-phase protonation of the neutral hydrocarbons in the CI(CH 4 ) plasma, has beenExpand

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Protonated 1,3,5‐cycloheptatriene and 7‐alkyl‐1,3,5‐cycloheptatrienes in the gas phase: ring contraction to the isomeric alkylbenzenium ions
1,3,5-Cycloheptatriene (1) and various 7-alkyl-1,3,5-cycloheptatrienes (3, 6, 9, 13, and 16-19) were subjected to gas-phase protonation under Cl(CH4) and Cl(iC(4)H(10)) conditions and the MIKEExpand
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The gas-phase basicities (GB) of 6-methylfulvene and 6,6-dimethylfulvene have been determined by Fourier transform ion cyclotron resonance spectrometry using the thermokinetic method. ProtonExpand
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The available data on gas-phase basicities and proton affinities of approximately 1700 molecular, radical and atomic neutral species are evaluated and compiled. Tables of the data are sorted (1)Expand
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