The extrapolation of experimental equilibrium constant data to zero ionic strength: Critical review and new approach.


Different Debye-Hückel expressions for the activity coefficients of species in aqueous solution in the ionic strength range I = 0-3.5m (3M) are used for the extrapolation of equilibrium constants data to I = 0 and the interpolation to unknown I values. This may be accomplished using four or more values of the equilibrium constants that are equally well… (More)


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