The electroreduction of benzyl cyanide on iron and cobalt cathodes

@article{Krishnan1979TheEO,
  title={The electroreduction of benzyl cyanide on iron and cobalt cathodes},
  author={Venkatasubramanian Krishnan and Arunachalam Muthukumaran and H. V. K. Udupa},
  journal={Journal of Applied Electrochemistry},
  year={1979},
  volume={9},
  pages={657-659}
}
An electrochemical method for preparing amines from organic cyanides using iron black and cobalt black cathodes has been studied. Benzyl cyanide underwent smooth reduction at a cobalt black cathode in an aqueous ethanolic ammonium sulphate medium to give a 74% yield of 2-phenylethylamine with a current efficiency of 50%; whereas with an iron black cathode under the same conditions, a 57% yield of 2-phenylethylamine has been obtained with a current efficiency of 33%. 
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References

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Electroreduction of benzonitrile
Benzylamine is used as a photographic fixing agent, as a corrosion inhibitor and also as a raw material for the preparation of powerful explosives which are easy to handle. The conventional methodExpand
On the electrochemical reduction of benzyl cyanide
The electro-reduction of benzonitrile to benzylamine has already been communicatedrf]. In the present communication, the electro-reduction of benzyl cyanide to o-phenylethylamine is described inExpand