The electronic ground state of [V(urea)6]3+ probed by NIR luminescence, electronic Raman, and high-field EPR spectroscopies.

Abstract

The electronic structure of a trigonally distorted vanadium(III) complex, [V(urea)6](ClO4)3, and its deuterated analogue, [V(urea-d4)6](ClO4)3 has been investigated with Raman, luminescence, and high-frequency high-field electron paramagnetic resonance spectroscopies and with magnetic measurements. A broad electronic Raman transition is observed at around… (More)

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