The effect of pH and hydrogen bond donor on the dissolution of metal oxides in deep eutectic solvents

@article{Pateli2020TheEO,
  title={The effect of pH and hydrogen bond donor on the dissolution of metal oxides in deep eutectic solvents},
  author={Ioanna Maria Pateli and Dana Thompson and Sahar S. M. Alabdullah and Andrew P. Abbott and Gawen R. T. Jenkin and Jennifer M. Hartley},
  journal={Green Chemistry},
  year={2020},
  volume={22},
  pages={5476-5486}
}
The dissolution behaviour of a series of d- and p-block metal oxides was investigated in deep eutectic solvents, DES, to determine the effect of pH and hydrogen bond donor (HBD) coordination strength on their solubility. The solubility of metal oxides was found to be increased by a higher proton activity in DESs composed of poorly complexing HBDs, due to the ability of H+ to act as an oxygen acceptor. However, the employment of HBDs that have stronger complexing abilities was proven to have a… 
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