The effect of low-temperature dynamics of the dimethylammonium group in [(CH3)2NH2]3Sb2Cl9 on proton spin-lattice relaxation and narrowing of the proton NMR line.

Abstract

This paper reports the temperature dependence of the relaxation time T1 (55.2 and 90 MHz) and the second moment of the NMR line for protons in a polycrystalline sample of [NH2(CH3)2]3Sb2Cl9 (DMACA). The fundamental aspects of molecular dynamics from quantum tunneling at low temperatures to thermally activated reorientation at elevated temperatures have been… (More)

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