# The double-layer structure of overscreened surfaces by smeared-out ions.

@article{Frydel2016TheDS, title={The double-layer structure of overscreened surfaces by smeared-out ions.}, author={Derek Frydel}, journal={The Journal of chemical physics}, year={2016}, volume={145 18}, pages={ 184703 } }

The present work focuses on the structure of a double-layer of overscreened charged surfaces by smeared-out charges and probes the link between the structure of a double-layer and the bulk properties of an electrolyte with special view to the role of the Kirkwood crossover. Just as the Kirkwood line divides a bulk solution into a fluid with monotonic and oscillatory decaying correlations, it similarly separates charge inversion into two broad domains, with and without oscillating charge density…

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