The double-layer structure of overscreened surfaces by smeared-out ions.

  title={The double-layer structure of overscreened surfaces by smeared-out ions.},
  author={Derek Frydel},
  journal={The Journal of chemical physics},
  volume={145 18},
  • D. Frydel
  • Published 2 September 2016
  • Physics
  • The Journal of chemical physics
The present work focuses on the structure of a double-layer of overscreened charged surfaces by smeared-out charges and probes the link between the structure of a double-layer and the bulk properties of an electrolyte with special view to the role of the Kirkwood crossover. Just as the Kirkwood line divides a bulk solution into a fluid with monotonic and oscillatory decaying correlations, it similarly separates charge inversion into two broad domains, with and without oscillating charge density… 
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