The current status of hydrogen storage in metal–organic frameworks

@article{Zhao2008TheCS,
  title={The current status of hydrogen storage in metal–organic frameworks},
  author={Dan Zhao and Daqiang Yuan and Hong‐Cai Zhou},
  journal={Energy and Environmental Science},
  year={2008},
  volume={1},
  pages={222-235}
}
The theoretical and experimental hydrogen storage studies on metal–organic frameworks (MOFs) have been reviewed. Seven distinct factors influencing hydrogen uptake capacity in MOFs have been classified and discussed. Based on existing studies, some possible future developments have been proposed. 
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References

SHOWING 1-10 OF 145 REFERENCES

Materials for hydrogen storage: current research trends and perspectives.

Main research trends on hydrogen storage materials, including metal hydrides, porous adsorbents and hydrogen clathrates, are reviewed with a focus on recent developments and an appraisal of the challenges ahead.

Strategies for hydrogen storage in metal--organic frameworks.

A discussion of several strategies aimed at improving hydrogen uptake in metal-organic frameworks, including the optimization of pore size and adsorption energy by linker modification, impregnation, catenation, and the inclusion of open metal sites and lighter metals.

Hydrogen storage in metal–organic frameworks

Hydrogen storage in metal–organic frameworks

For any potential hydrogen-storage system, raw uptake capacity must be balanced with the kinetics and thermodynamics of uptake and release. Metal–organic frameworks (MOFs) provide unique systems with…

Hydrogen storage in metal-organic frameworks by bridged hydrogen spillover.

Substantially increased hydrogen storage capacities of modified MOFs are reported by using a simple technique that causes and facilitates hydrogen spillover.

Improved Hydrogen Storage in the Metal‐Organic Framework Cu3(BTC)2

A new pressure-free synthesis method was developed producing the porous material Cu 3 (BTC) 2 (BTC = benzene tricarboxylate) with a very high micropore volume up to 0.62 cm 3 g -1 . The compound is a…

Improved hydrogen storage in the modified metal-organic frameworks by hydrogen spillover effect

Desorption studies of hydrogen in metal-organic frameworks.

The correlation between the desorption spectra and the pore structure of these MOFs shows that at high hydrogen concentrations the diameter of the cavity determines the heat of adsorption.

Improving hydrogen storage capacity of MOF by functionalization of the organic linker with lithium atoms.

Ab initio calculations showed that the interaction energies between the hydrogen molecules and this functional group are up to three times larger compared with unmodified MOF, and this trend was verified by grand canonical Monte Carlo simulations in various thermodynamic conditions.

Framework-catenation isomerism in metal-organic frameworks and its impact on hydrogen uptake.

A strategy to control framework-catenation in MOFs has been presented; contributions to hydrogen uptake from interpenetration and unsaturated metal centers have been resolved.
...