The current status of hydrogen storage in metal–organic frameworks

@article{Zhao2008TheCS,
  title={The current status of hydrogen storage in metal–organic frameworks},
  author={Dan Zhao and Daqiang Yuan and Hong‐Cai Zhou},
  journal={Energy and Environmental Science},
  year={2008},
  volume={1},
  pages={222-235}
}
The theoretical and experimental hydrogen storage studies on metal–organic frameworks (MOFs) have been reviewed. Seven distinct factors influencing hydrogen uptake capacity in MOFs have been classified and discussed. Based on existing studies, some possible future developments have been proposed. 
View via Publisher
apps.dtic.mil
382 Citations
Highly Influential Citations
2
Background Citations
15
Methods Citations
1
Results Citations
2

Figures from this paper

382 Citations

Hydrogen storage in Co-and Zn-based metal-organic frameworks at ambient temperature

The current status of hydrogen storage in metal–organic frameworks—updated

Hydrogen storage in metal–organic frameworks (MOFs), or porous coordination polymers, has been extensively investigated in the last two years and this review is to serve as an up to date account of…

Hydrogen storage in metal–organic frameworks

For any potential hydrogen-storage system, raw uptake capacity must be balanced with the kinetics and thermodynamics of uptake and release. Metal–organic frameworks (MOFs) provide unique systems with…

Optimized synthesis of Zr(iv) metal organic frameworks (MOFs-808) for efficient hydrogen storage

The optimized MOF-808 exhibited relatively high chemical stability and excellent hydrogen storage properties at different temperatures.

Strategies for Hydrogen Storage in Porous Organic Polymers

Gas storage by using porous materials has been a hot research topic in recent years. In this review, we highlight advances in porous organic polymers for their hydrogen storage applications.

Hydrogen storage in metal-organic frameworks.

This critical review of the current status of hydrogen storage within microporous metal-organic frameworks provides an overview of the relationships between structural features and the enthalpy of hydrogen adsorption, spectroscopic methods for probing framework-H(2) interactions, and strategies for improving storage capacity.

Materials for Hydrogen storage and synthesis of new materials by hydrogenation

The search for new materials for hydrogen storage is important for the development of future hydrogen energy applications. In this Thesis, it is shown that new materials with interesting properties…

Storage of Hydrogen on Nanoporous Adsorbents

The adsorption of hydrogen has extensively been studied on various nanoporous adsorbents with the driving force being the need to safely store this increasingly important energy vector. This chapter…

Hydrogen physisorption in metal–organic frameworks: concepts and quantum chemical calculations

Storage of hydrogen by physisorption in metal–organic frameworks is reviewed from the perspective of quantum chemistry. Concepts regarding the interaction of hydrogen with metals are revised and the…

Development of amidoboranes for hydrogen storage.

This review provides a practical introduction to the recent progress on the syntheses, crystal structures and dehydrogenation properties of metal amidoboranes and their derivatives.
...

References

SHOWING 1-10 OF 145 REFERENCES

Materials for hydrogen storage: current research trends and perspectives.

Main research trends on hydrogen storage materials, including metal hydrides, porous adsorbents and hydrogen clathrates, are reviewed with a focus on recent developments and an appraisal of the challenges ahead.

Strategies for hydrogen storage in metal--organic frameworks.

A discussion of several strategies aimed at improving hydrogen uptake in metal-organic frameworks, including the optimization of pore size and adsorption energy by linker modification, impregnation, catenation, and the inclusion of open metal sites and lighter metals.

Hydrogen storage in metal–organic frameworks

Hydrogen storage in metal–organic frameworks

For any potential hydrogen-storage system, raw uptake capacity must be balanced with the kinetics and thermodynamics of uptake and release. Metal–organic frameworks (MOFs) provide unique systems with…

Improved Hydrogen Storage in the Metal‐Organic Framework Cu3(BTC)2

A new pressure-free synthesis method was developed producing the porous material Cu 3 (BTC) 2 (BTC = benzene tricarboxylate) with a very high micropore volume up to 0.62 cm 3 g -1 . The compound is a…

Improved hydrogen storage in the modified metal-organic frameworks by hydrogen spillover effect

Desorption studies of hydrogen in metal-organic frameworks.

The correlation between the desorption spectra and the pore structure of these MOFs shows that at high hydrogen concentrations the diameter of the cavity determines the heat of adsorption.

Improving hydrogen storage capacity of MOF by functionalization of the organic linker with lithium atoms.

Ab initio calculations showed that the interaction energies between the hydrogen molecules and this functional group are up to three times larger compared with unmodified MOF, and this trend was verified by grand canonical Monte Carlo simulations in various thermodynamic conditions.

Framework-catenation isomerism in metal-organic frameworks and its impact on hydrogen uptake.

A strategy to control framework-catenation in MOFs has been presented; contributions to hydrogen uptake from interpenetration and unsaturated metal centers have been resolved.

Significantly enhanced hydrogen storage in metal-organic frameworks via spillover.

This work reports, for the first time, significant amounts of hydrogen storage in MOF-5 and IRMOF-8 at ambient temperature by using a very simple technique via hydrogen dissociation and spillover, and suggests that the technique is suitable for hydrogenstorage in a variety of MOF materials because of their similar structures.
...