The conical intersection dominates the generation of tropospheric hydroxyl radicals from NO2 and H2O.

Abstract

In the present work, we report a quantitative understanding on how to generate hydroxyl radicals from NO(2) and H(2)O in the troposphere upon photoexcitation at 410 nm by using multiconfigurational perturbation theory and density functional theory. The conical intersections dominate the nonadiabatic relaxation processes after NO(2) irradiated at… (More)
DOI: 10.1021/jp911455r

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Cite this paper

@article{Fang2010TheCI, title={The conical intersection dominates the generation of tropospheric hydroxyl radicals from NO2 and H2O.}, author={Qiu Fang and Juan Han and Jieling Jiang and Xuebo Chen and Weihai Fang}, journal={The journal of physical chemistry. A}, year={2010}, volume={114 13}, pages={4601-8} }