995 Citations
Determination of kinetic parameters of redox reactions using CE‐ICP‐MS: A case study for the reduction of Np(V) by hydroxylamine hydrochloride
- ChemistryElectrophoresis
- 2018
The results and a comparison with literature data show that the coupling of CE to ICP‐MS provides a powerful analytical tool for the investigation of the kinetic aspects of redox reactions of actinides at low concentrations, and the method presented here can be extended to the investigationof the kinetic parameters of other redox systems containing different actinide (or transition metals) and oxidants/reductants.
Quantifying Aqueous Plutonium Using Hybrid Extractive Scintillation Resins
- Materials Science
- 2018
Expanding the Chemistry of Molecular U(2+) Complexes: Synthesis, Characterization, and Reactivity of the {[C5 H3 (SiMe3 )2 ]3 U}(-) Anion.
- ChemistryChemistry
- 2016
Variable temperature magnetic susceptibility data for 1 and 2-K(crypt) reveal lower room temperature χM T values relative to the experimental values for the 5f(3) U(3+) precursors, as well as stability studies monitored by UV/Vis spectroscopy.
C 5 H 3 ( SiMe 3 ) 2 ] 3 U } ¢ Anion
- Chemistry
- 2015
The synthesis of new molecular complexes of U + has been pursued to make comparisons in structure, physical properties, and reactivity with the first U + complex, [K(2.2.2-cryptand)][Cp’3U], 1 (Cp’=…
Electrochemical, computational and spectroscopic investigation on local environment of plutonium in ionic liquid and aqueous medium: a comparative study
- Chemistry
- 2015
Abstract With an aim to understand the nature of species, cyclic voltammetry (CV) of Pu(IV) in dilute HBr and in a room temperature ionic liquid (RTIL), 1-octyl-3-methylimidazolium bromide (C8mimBr)…
Uranium Complexes Expanding the Chemistry of Molecular U 2 + Complexes : Synthesis , Characterization , and Reactivity of the { [ C 5 H 3 ( SiMe 3 ) 2 ] 3 U } ¢ Anion
- Chemistry
- 2015
The synthesis of new molecular complexes of U + has been pursued to make comparisons in structure, physical properties, and reactivity with the first U + complex, [K(2.2.2-cryptand)][Cp’3U], 1 (Cp’=…
URANYL REACTIONS WITH DITHIONITE, L-ASCORBIC ACID, AND SUPPORTED NANOSIZED ZERO-VALENT IRON
- Chemistry
- 2011
Plutonium - Humic Acid Stability Constant Determination and Subsequent Studies Examining Sorption in the Ternary Pu(IV) - Humic Acid - Gibbsite System
- Environmental Science
- 2010
Advances in actinide thin films: synthesis, properties, and future directions
- Physics
- 2022
Actinide-based compounds exhibit unique physics due to the presence of 5 f electrons, and serve in many cases as important technological materials. Targeted thin film synthesis of actinide materials…
Extrapolation Estimates of the Physicochemical Parameters of Nichonium, Tennessin, and Oganesson
- ChemistryRadiochemistry
- 2021
The method of comparative calculation, based on the correlation of some properties with others in the group of analogous elements and which has been repeatedly utilized to determine the properties of…