The adsorption enthalpy of nitrogen oxides on crystalline ice

  title={The adsorption enthalpy of nitrogen oxides on crystalline ice},
  author={Thorsten Bartels-Rausch and Barbara Eichler and Peter Zimmermann and Heinz W Gaeggeler and Markus Ammann},
The partitioning of nitrogen oxides between ice and air is important to the ozone budget in the upper troposphere. In the present study, the adsorption of nitrogen oxides on ice was investigated at atmospheric pressure using a chromatographic technique with low concentrations of radioactively labelled nitrogen oxides. The measured retentions solely depended on molecular adsorption and were not influenced by dimerisation, formation of encapsulated hydrates on the ice surface, dissociation of the… CONTINUE READING
10 Citations
57 References
Similar Papers


Publications citing this paper.
Showing 1-10 of 10 extracted citations


Publications referenced by this paper.
Showing 1-10 of 57 references

Heterogeneous interaction and reaction of HONO on ice films between 173 and 230 K

  • L. Chu, G. Diao, L. T. Chu
  • J. Phys. Chem. A,
  • 2000
Highly Influential
3 Excerpts

A surface chemistry model for nonractive trace gas adsorption on ice: Implications for nitric acid scavening by cirrus

  • A. Tabazadeh, O. B. Toon, E. J. Jensen
  • Geophys. Res. Letts.,
  • 1999
Highly Influential
3 Excerpts

Interaction of HNO 3 with waterice surfaces at temperatures of the free troposphere

  • J. P. D. Abbatt
  • Res . Letts .
  • 1997
Highly Influential
1 Excerpt

NO adsorption on ice at low concentrations

  • R. A. Sommerfeld, M. H. Conklin, S. K. Laird
  • J. Colloid and Interface Science,
  • 1992
Highly Influential
5 Excerpts

Adsorption of Atmos

  • B. Eichler, H. P. Zimmermann, H. Gäggeler
  • Chem . Phys .
  • 2002

Measurement of the specific surface area of 176 snow samples using methane adsorption at 77

  • F. é
  • K, J. Geophys. Res., in press,
  • 2002

Molecular atmospheric pollutant adsorption on ice: a theoretical survey

  • C. Girardet, C. Toubin
  • Surface Science Reports,
  • 2001
1 Excerpt

Using13N as tracer in heterogeneous atmospheric chemistry experiments

  • M. Ammann
  • Radiochimica Acta,
  • 2001
4 Excerpts

Similar Papers

Loading similar papers…