The Ternary Alkaline-Earth Metal Manganese Bismuthides Sr2MnBi2 and Ba2Mn1-xBi2 (x ≈ 0.15).


Two new ternary manganese bismuthides have been synthesized and their structures established based on single-crystal X-ray diffraction methods. Sr2MnBi2 crystallizes in the orthorhombic space group Pnma (a = 16.200(9) Å, b = 14.767(8) Å, c = 8.438(5) Å, V = 2018(2) Å3; Z = 12; Pearson index oP60) and is isostructural to the antimonide Sr2MnSb2. The crystal… (More)
DOI: 10.1021/acs.inorgchem.7b01851