The Structure of the Tetraphenyldithioimidodiphosphinate Ion


Bis(diphenylthiophosphoryl)amine, a weak protic acid, can be readily deprotonated. The alkali salts [Ph2P(S)]2NM have been used to prepare S-bonded complexes with transition metals containing a NP2S2M six membered ring [1]. Although the struc­ tures of the neutral ligand [Ph2P(S)]2NH [2] and of several transition metal complexes [1] have been de­ termined… (More)


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