The Palladium-Catalyzed Intramolecular Alder-Ene Reactions of O- and N-Linked 1,6-Enynes Incorporating Triethylsilyl Capping Groups.

Abstract

A series of O- and N-linked 1,6-enynes (e.g., 11) have been prepared with each subjected to a palladium-catalyzed intramolecular Alder-ene (IMAE) reaction, thus producing the isomeric and cyclic 1,4-diene (e.g., 12). These processes proceed most effectively when a triethylsilyl group is attached to the alkyne moiety and so generating alkenylsilanes that can… (More)
DOI: 10.1021/acs.joc.7b02355

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Cite this paper

@article{Nugent2017ThePI, title={The Palladium-Catalyzed Intramolecular Alder-Ene Reactions of O- and N-Linked 1,6-Enynes Incorporating Triethylsilyl Capping Groups.}, author={Jeremy Nugent and Eli{\vs}ka Matou{\vs}ov{\'a} and Martin G Banwell and A nthony C. Willis}, journal={The Journal of organic chemistry}, year={2017}, volume={82 23}, pages={12569-12589} }