The MOF-driven synthesis of supported palladium clusters with catalytic activity for carbene-mediated chemistry.

Abstract

The development of catalysts able to assist industrially important chemical processes is a topic of high importance. In view of the catalytic capabilities of small metal clusters, research efforts are being focused on the synthesis of novel catalysts bearing such active sites. Here we report a heterogeneous catalyst consisting of Pd4 clusters with mixed… (More)
DOI: 10.1038/nmat4910

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