The Influence of t-Butyl and Cyclododecyl Substitution on Ethylene / 1-Hexene Copolymerization Using Ansa-Fluorenylamidodimethyltitanium Derivatives

@inproceedings{Kaivalchatchawal2011TheIO,
  title={The Influence of t-Butyl and Cyclododecyl Substitution on Ethylene / 1-Hexene Copolymerization Using Ansa-Fluorenylamidodimethyltitanium Derivatives},
  author={Patcharaporn Kaivalchatchawal and Piyasan Praserthdam and Yuuichi Sogo and Zhengguo Cai and Takeshi Shiono and Bunjerd Jongsomjit},
  year={2011}
}
In the present study, copolymerization of ethylene and 1-hexene was conducted with a series of ansa-fluorenylamidodimethyltitanium complexes, including [t-BuNSiMe2Flu]TiMe2 (complex 1), [cyclododecylNSiMe2Flu]TiMe2 (complex 2) and [t-BuNSiMe2(2,7-t-Bu2Flu)]TiMe2 (complex 3), activated by MMAO. The effect of these catalysts on catalytic behavior, namely… CONTINUE READING