The First Synthesis of 3-epi-Xestoaminol C

@article{Choi2015TheFS,
  title={The First Synthesis of 3-epi-Xestoaminol C},
  author={J. Choi and H. Ha},
  journal={Journal of The Korean Chemical Society},
  year={2015},
  volume={59},
  pages={203-204}
}
  • J. Choi, H. Ha
  • Published 2015
  • Chemistry
  • Journal of The Korean Chemical Society
A new 1-deoxysphingoid, 3-epi-xestoaminol C (1), isolated from the New Zealand brown alga Xiphophora chondrophylla was firstly synthesized for the identification of its absolute stereochemistry via stereoselective reduction of 2-acylaziridine followed by hydrogenolysis. Sphingosine as a class of lipid described almost two centuries ago 1 was characterized structurally as 2-amino-1,3diol in long alkyl chain most of which participate in cell structure and its regulation. 2 Up to now hundreds of… Expand
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