The Effect of Temperature on Kinetics and Diffusion Coefficients of Metallocene Derivatives in Polyol-Based Deep Eutectic Solvents.

@article{Bahadori2015TheEO,
  title={The Effect of Temperature on Kinetics and Diffusion Coefficients of Metallocene Derivatives in Polyol-Based Deep Eutectic Solvents.},
  author={Laleh Bahadori and Mohammed Harun Chakrabarti and Ninie Suhana Abdul Manan and Mohd Ali Hashim and Farouq Sabri Mjalli and I. M. Alnashef and Nigel P. Brandon},
  journal={PloS one},
  year={2015},
  volume={10 12},
  pages={e0144235}
}
The temperature dependence of the density, dynamic viscosity and ionic conductivity of several deep eutectic solvents (DESs) containing ammonium-based salts and hydrogen bond donvnors (polyol type) are investigated. The temperature-dependent electrolyte viscosity as a function of molar conductivity is correlated by means of Walden's rule. The oxidation of ferrocene (Fc/Fc+) and reduction of cobaltocenium (Cc+/Cc) at different temperatures are studied by cyclic voltammetry and potential-step… CONTINUE READING