The Development of Alkoxide-Directed Metallacycle-Mediated Annulative Cross-Coupling Chemistry.

@article{Micalizio2017TheDO,
  title={The Development of Alkoxide-Directed Metallacycle-Mediated Annulative Cross-Coupling Chemistry.},
  author={Glenn C. Micalizio and Haruki Mizoguchi},
  journal={Israel journal of chemistry},
  year={2017},
  volume={57 3-4},
  pages={
          228-238
        }
}
Alkoxide-directed metallacycle-mediated cross-coupling is a rapidly growing area of reaction methodology in organic chemistry. Over the last decade, developments have resulted in > thirty new and highly selective intermolecular (or "convergent") C-C bond-forming reactions that have established powerful retrosynthetic relationships in stereoselective synthesis. While early studies were focused on developing transformations that forge a single C-C bond by way of a functionalized and unsaturated… Expand
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