The Cyclic Voltammetry Simulation of a Competition Between Stepwise and Concerted Dissociative Electron Transfer, the Modeling of Alpha Apparent Variability, the Relationship Between Apparent and Elementary Kinetic Parameters


A comparison of elementary (input) and apparent (output) values of the transfer coefficient was carried out for simulated kinetic cyclic voltammetry spectrum from stepwise to concerted mechanism. The resulting patterns of alphaapp versus Ep plots do not provide sufficient information to discriminate between the two mechanisms. It has been demonstrated that… (More)
DOI: 10.1016/S0097-8485(01)00123-1