The ALMA-PILS survey: First detections of deuterated formamide and deuterated isocyanic acid in the interstellar medium

  title={The ALMA-PILS survey: First detections of deuterated formamide and deuterated isocyanic acid in the interstellar medium},
  author={Audrey Coutens and Jes K. J{\o}rgensen and Matthijs van der Wiel and Holger S. P. Muller and Julie M. Lykke and Per Bjerkeli and Tyler L. Bourke and Hannah Calcutt and Maria Nikolayevna Drozdovskaya and C{\'e}cile Favre and Edith C. Fayolle and Robin T. Garrod and Steffen K. Jacobsen and Niels F. W. Ligterink and Karin I. Oberg and Magnus Persson and Ewine F. van Dishoeck and Susanne F. Wampfler},
  journal={Astronomy and Astrophysics},
Formamide (NH2CHO) has previously been detected in several star-forming regions and is thought to be a precursor for different prebiotic molecules. Its formation mechanism is still debated, however. Observations of formamide, related species, and their isopotologues may provide useful clues to the chemical pathways leading to their formation. The Protostellar Interferometric Line Survey (PILS) represents an unbiased, high angular resolution and sensitivity spectral survey of the low-mass… 

The ALMA-PILS survey: the first detection of doubly deuterated methyl formate (CHD2OCHO) in the ISM

Studies of deuterated isotopologues of complex organic molecules can provide important constraints on their origin in star formation regions. In particular, the abundances of deuterated species are

The ALMA-PILS survey: first detection of methyl isocyanide (CH3NC) in a solar-type protostar

Context. Methyl isocyanide (CH3NC) is the isocyanide with the largest number of atoms confirmed in the interstellar medium (ISM), but it is not an abundant molecule, having only been detected towards

The ALMA-PILS survey: propyne (CH3CCH) in IRAS 16293–2422

Context. Propyne (CH3CCH), also known as methyl acetylene, has been detected in a variety of environments, from Galactic star-forming regions to extragalactic sources. These molecules are excellent

The ALMA-PILS survey: detection of CH3NCO towards the low-mass protostar IRAS 16293−2422 and laboratory constraints on its formation

Methyl isocyanate (CH3NCO) belongs to a select group of interstellar molecules considered to be relevant precursors in the formation of larger organic compounds, including those with peptide bonds.

First detection of cyanamide (NH2CN) towards solar-type protostars

Searches for the prebiotically relevant cyanamide (NH 2 CN) towards solar-type protostars have not been reported in the literature. We present here the first detection of this species in the warm gas

The ALMA-PILS survey: isotopic composition of oxygen-containing complex organic molecules toward IRAS 16293–2422B

Context. One of the important questions of astrochemistry is how complex organic molecules, including potential prebiotic species, are formed in the envelopes around embedded protostars. The

The ALMA-PILS survey: First detections of ethylene oxide, acetone and propanal toward the low-mass protostar IRAS 16293-2422

Context. One of the open questions in astrochemistry is how complex organic and prebiotic molecules are formed. The unsurpassed sensitivity of the Atacama Large Millimeter/submillimeter Array (ALMA)

The ALMA-PILS survey: First detection of nitrous acid (HONO) in the interstellar medium

Nitrogen oxides are thought to play a significant role as a nitrogen reservoir and to potentially participate in the formation of more complex species. Until now, only NO, N2O, and HNO have been

The ALMA-PILS survey: Stringent limits on small amines and nitrogen-oxides towards IRAS 16293–2422B

Context. Hydroxylamine (NH2OH) and methylamine (CH3NH2) have both been suggested as precursors to the formation of amino acids and are therefore, of interest to prebiotic chemistry. Their presence in

Protostellar and cometary detections of organohalogens

Organohalogens, a class of molecules that contain at least one halogen atom bonded to carbon, are abundant on the Earth where they are mainly produced through industrial and biological processes1.



Shedding light on the formation of the pre-biotic molecule formamide with ASAI

Formamide (NH2CHO) has been proposed as a pre-biotic precursor with a key role in the emergence of life on Earth. While this molecule has been observed in space, most of its detections correspond to

The extended spectroscopic database for deuterated species of formamide up to 1 THz

Context. Formamide (HCONH2) is the simplest molecule with a peptide bond detected in the interstellar medium. One of the keys for understanding the mechanisms for forming formamide in massive hot

TIMASSS: the IRAS16293-2422 millimeter and submillimeter spectral survey: tentative detection of deuterated methyl formate (DCOOCH3)

Context. High deuterium fractionation is observed in various types of environments such as prestellar cores, hot cores, and hot corinos. It has proven to be an efficient probe for studying the

Tentative identification of urea and formamide in ISO-SWS infrared spectra of interstellar ices

Laboratory experiments involving vacuum ultraviolet (VUV) irradiation of solid isocyanic acid (HNCO) at 10 K, followed by infrared spectroscopy (FTIR), are used to interpret the complex spectra

A study of deuterated water in the low-mass protostar IRAS 16293-2422

Context. Water is a primordial species in the emergence of life, and comets may have brought a large fraction to Earth to form the oceans. To understand the evolution of water from the first stages


Glycolaldehyde (HCOCH2OH) is the simplest sugar and an important intermediate in the path toward forming more complex biologically relevant molecules. In this Letter we present the first detection of

Gas-phase formation of the prebiotic molecule formamide: insights from new quantum computations

It is shown that the proposed mechanism can well reproduce the abundances of formamide observed in two very different interstellar objects: the cold envelope of the Sun-like protostar IRAS16293-2422 and the molecular shock L1157-B2.

Synthesis of formamide and isocyanic acid after ion irradiation of frozen gas mixtures

Context. Formamide (NH2HCO) and isocyanic acid (HNCO) have been observed as gaseous species in several astronomical environments such as cometary comae and preand proto-stellar objects. A debate is

Heavy water stratification in a low-mass protostar

Context. Despite the low elemental deuterium abundance in the Galaxy, enhanced molecular deuterium fractionation has been found in the environments of low-mass star-forming regions and, in

Molecules with a peptide link in protostellar shocks: a comprehensive study of L1157

Interstellar molecules with a peptide link -NH-C(=O)-, like formamide (NH$_2$CHO), acetamide (NH$_2$COCH$_3$) and isocyanic acid (HNCO) are particularly interesting for their potential role in