The Ã-state dissociation continuum of NO-Ar and its near infrared spectrum.

  title={The {\~A}-state dissociation continuum of NO-Ar and its near infrared spectrum.},
  author={Henning Meyer},
  journal={The Journal of chemical physics},
  volume={136 20},
After preparing NO-Ar in a vibrational state correlating with the first overtone vibration in NO, we recorded its hot band UV spectrum by monitoring simultaneously the intensity in the NO(+) and the NO(+)-Ar ion channels. In this way, the bound as well as the continuous part of the electronic Ã←X̃ spectrum are observed directly. Below the dissociation threshold, the intensity is found exclusively in the NO(+)-Ar ion channel while above it is found in the NO fragment ion channel. We observe… CONTINUE READING

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