Thallophilic interactions in aryloxide compounds: the [Tl2(mu2-OAr)4] structural motif in (TlOAr)4 and Tl2Cu(OAr)4 compounds.

@article{Childress2006ThallophilicII,
  title={Thallophilic interactions in aryloxide compounds: the [Tl2(mu2-OAr)4] structural motif in (TlOAr)4 and Tl2Cu(OAr)4 compounds.},
  author={Montana V Childress and David Millar and T. Alam and Kevin A. Kreisel and G. Yap and L. Zakharov and J. Golen and A. Rheingold and L. Doerrer},
  journal={Inorganic chemistry},
  year={2006},
  volume={45 10},
  pages={
          3864-77
        }
}
Two thallium aryloxide compounds TlOC6F5 (TlOAr(F)) and bis-3,5-TlOC6H3(CF3)2 (TlOAr') have been recrystallized from THF and crystallographically characterized in different isomeric forms. The latter compound forms a solvated tetrameric cubane, [TlOAr']4.THF, 1. The TlOAr(F) compound crystallized with a similar stoichiometry, [TlOAr(F)]4.2 THF, 2, but contains a [Tl2(mu2-OAr(F))4] unit that includes a thallophilic interaction at a distance of 3.5943(15) angstroms. Solution 205Tl and 203Tl NMR… Expand
Three-coordinate late transition metal fluorinated alkoxide complexes.
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