Tetra-ortho-substituted biaryls through palladium-catalyzed Suzuki-Miyaura couplings with a diaminochlorophosphine ligand.

Abstract

A palladium complex derived from a sterically hindered diaminochlorophosphine allowed for Suzuki-Miyaura cross-couplings of chloroarenes with ample scope and provided access to tetra-ortho-substituted bi(hetero)aryls.

DOI: 10.1021/ol1000186

Cite this paper

@article{Ackermann2010TetraorthosubstitutedBT, title={Tetra-ortho-substituted biaryls through palladium-catalyzed Suzuki-Miyaura couplings with a diaminochlorophosphine ligand.}, author={Lutz Ackermann and Harish Kumar Potukuchi and Andreas Althammer and Robert Born and Peter Mayer}, journal={Organic letters}, year={2010}, volume={12 5}, pages={1004-7} }