Template-directed synthesis of nets based upon octahemioctahedral cages that encapsulate catalytically active metalloporphyrins.

@article{Zhang2012TemplatedirectedSO,
  title={Template-directed synthesis of nets based upon octahemioctahedral cages that encapsulate catalytically active metalloporphyrins.},
  author={Zhenjie Zhang and Linping Zhang and Lukasz Wojtas and Mohamed Eddaoudi and Michael J Zaworotko},
  journal={Journal of the American Chemical Society},
  year={2012},
  volume={134 2},
  pages={928-33}
}
meso-Tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) templates the synthesis of six new metal-organic materials by the reaction of benzene-1,3,5-tricarboxylate with transition metals, five of which exhibit HKUST-1 or tbo topology (M = Fe, Mn, Co, Ni, Mg). The resulting materials, porph@MOMs, selectively encapsulate the corresponding metalloporphyrins in octahemioctahedral cages and can serve as size-selective heterogeneous catalysts for oxidation of olefins. 
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