Template-controlled synthesis of a planar [16]ane-P2C(NHC)2 macrocycle.

@article{FloresFigueroa2010TemplatecontrolledSO,
  title={Template-controlled synthesis of a planar [16]ane-P2C(NHC)2 macrocycle.},
  author={Aar{\'o}n Flores-Figueroa and Tania Pape and Kai‐Oliver Feldmann and F. Ekkehardt Hahn},
  journal={Chemical communications},
  year={2010},
  volume={46 2},
  pages={
          324-6
        }
}
Reaction of tetraphosphine platinum(II) complexes with 2-azidoethyl isocyanide 3 in methanol leads to complexes with two trans-coordinated NH,NH-stabilized carbene ligands 6(X)(2). Complexes 6(X)(2) react with phenyldivinylphosphine under substitution of the remaining phosphine ligands followed by an intramolecular hydroamination reaction to produce complex 1(PF(6))(2) with a macrocyclic [16]ane-P(2)C(NHC)(2) ligand. 
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72 Citations

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