Temperature-hydrogen pressure phase boundaries and corresponding thermodynamics for ZrCoH system

@article{Kou2018TemperaturehydrogenPP,
  title={Temperature-hydrogen pressure phase boundaries and corresponding thermodynamics for ZrCoH system},
  author={Huaqin Kou and Wenhua Luo and Tao Tang and Zhiyong Huang and Ge Sang and Huan Wang and Chang An Chen and Guanghui Zhang and Jinchun Bao and Xue Yan},
  journal={International Journal of Hydrogen Energy},
  year={2018},
  volume={43},
  pages={16169-16179}
}
Abstract The thermodynamically and kinetically stable regions of the temperature–H2 pressure phase boundaries for the ZrCo H system were established using the Temperature-Concentration-Isobar (TCI) method. Based on this, the enthalpy change and entropy change values of dehydrogenation and disproportionation reactions were successfully obtained. The average enthalpy change (ΔH) and entropy change (ΔS) estimated from the phase boundaries for dehydrogenation of ZrCoH3 to ZrCo are respectively 103… Expand
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