Temperature-dependent assemblies from a 2-D triple-stranded meso-helical layer to a 3-D chain-layer metal-organic framework.

Abstract

Two different crystal forms, namely {[Dy2(mpda)3(H2O)2]·H2O}n (1) and [Dy2(mpda)3(H2O)4]n (2), were obtained from the reaction of multidentate 2,6-dimethylpyridine-3,5-dicarboxylic acid (H2mpda) with Dy2O3 at different temperatures. Structural analysis reveals that compound 1 is a 2-D triple-stranded meso-helical layer, and 2 a 3-D chain-layer framework… (More)
DOI: 10.1039/c2dt32234j

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Cite this paper

@article{Jin2012TemperaturedependentAF, title={Temperature-dependent assemblies from a 2-D triple-stranded meso-helical layer to a 3-D chain-layer metal-organic framework.}, author={Hong-Guang Jin and Xu-Jia Hong and Jing Jian Li and Yuan-Zhao Yan and Yi-Ting Liu and Shi-hai Xu and Yuepeng Cai}, journal={Dalton transactions}, year={2012}, volume={41 47}, pages={14239-43} }