Temperature dependence of ion transport: the compensated Arrhenius equation.

@article{Petrowsky2009TemperatureDO,
  title={Temperature dependence of ion transport: the compensated Arrhenius equation.},
  author={Matt Petrowsky and Roger Frech},
  journal={The journal of physical chemistry. B},
  year={2009},
  volume={113 17},
  pages={5996-6000}
}
The temperature-dependent conductivity originating in a thermally activated process is often described by a simple Arrhenius expression. However, this expression provides a poor description of the data for organic liquid electrolytes and amorphous polymer electrolytes. Here, we write the temperature dependence of the conductivity as an Arrhenius expression and show that the experimentally observed non-Arrhenius behavior is due to the temperature dependence of the dielectric constant contained… CONTINUE READING
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