Temperature- and pressure-induced phase transitions in the metal formate framework of [ND₄][Zn(DCOO)₃] and [NH₄][Zn(HCOO)₃].


Vibrational properties and the temperature-induced phase transition mechanism have been studied in [NH4][Zn(HCOO)3] and [ND4][Zn(DCOO)3] metal organic frameworks by variable-temperature dielectric, IR, and Raman measurements. DFT calculations allowed proposing the detailed assignment of vibrational modes to respective motions of atoms in the unit cell… (More)
DOI: 10.1021/ic501074x


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