Temperature and concentration control over interpenetration in a metal-organic material.

  title={Temperature and concentration control over interpenetration in a metal-organic material.},
  author={Jianjun Zhang and Lukasz Wojtas and Randy W. Larsen and Mohamed Eddaoudi and Michael J Zaworotko},
  journal={Journal of the American Chemical Society},
  volume={131 47},
A pillared framework formed from 4,4'-bipyridine (bipy) and sheets of dinuclear Cd(2) nodes and 1,4-benzenedicarboxylic acid (bdc) linkers can be prepared in both interpenetrated and noninterpenetrated forms by simply varying the temperature or concentration of the reaction. These results demonstrate that higher temperatures and concentrations favor interpenetration over the corresponding noninterpenetrating structure, an observation that could have broad implications for controlling the… CONTINUE READING

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Crystal data for 1: C27H35N5O8Cd, Orthorhombic, Pbam

J. Chem.sEur
Dalton Trans. 2000, • 2005

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