TOTAL SYNTHESIS OF FK‐156 ISOLATED FROM A STREPTOMYCES AS AN IMMUNOSTIMULATING PEPTIDE: APPLICATION OF A NOVEL COPPER CHELATE AMINO PROTECTION

@inproceedings{Hemmi1981TOTALSO,
  title={TOTAL SYNTHESIS OF FK‐156 ISOLATED FROM A STREPTOMYCES AS AN IMMUNOSTIMULATING PEPTIDE: APPLICATION OF A NOVEL COPPER CHELATE AMINO PROTECTION},
  author={Keiji Hemmi and Hidekazu Takeno and Satoshi Okada and Osamu Nakaguchi and Yoshihiko Kitaura and Masashi Hashimoto},
  year={1981}
}
Das Derivat (I) (Darstellung beschrieben) der entsprechenden (synthetisch zuganglichen) meso-Diamino-pimelinsaure wird enzymatisch hydrolysiert; selektiver Schutz der Aminogruppen im Produkt (IIa) unter Cu-chelat-Bedingungen liefert die Verbindung (IIb).