TMS Triflate‐Promoted O‐Glycosylation of Amino Acids and Peptides by L‐Acosaminal and L‐Ristosaminal

@inproceedings{Kessler1994TMSTO,
  title={TMS Triflate‐Promoted O‐Glycosylation of Amino Acids and Peptides by L‐Acosaminal and L‐Ristosaminal},
  author={Horst Kessler and K Iwama Michael and Matthias Kottenhahn},
  year={1994}
}
Cyclic and linear peptides are stereoselectively O-glycosylated by 3-(acylamino)glycals through activation with TMS triflate (trimethylsilyl trifluoromethanesulfonate) without Ferrier rearrangement. The yields of the 2-deoxy-α-O-glycosides obtained range from 18 to 95%.