THE DISPROPORTIONATION OF ZIRCONIUM TRICHLORIDE

@inproceedings{Turnbull1963THEDO,
  title={THE DISPROPORTIONATION OF ZIRCONIUM TRICHLORIDE},
  author={Ag Turnbull and Ja Watts},
  year={1963}
}
Equilibrium pressures of the reaction 2ZrCl/sub 3/(c) yields ZrCl/sub 2/ (c) + ZrCl/sub 4/(g) measured by a cooling curve modification of the dew-point technique was fitted over the range 613--723 deg K, by the relation log/sub 10/p/ sub mm/=-6246/T + 11.632 plus or minus 0.05 (S.D.). Derived thermochemical data are DELTA H/sub 298/ = 30.1 plus or minus 0.5 kcal and DELTA S/sub 298/ = 39.1 plus or minus 1 eu, consistent with estimated DELTA Hf/sub 298/ZrCl/sub 3/ =-186 kcal/mole and DELTA Hf… CONTINUE READING

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References

Publications referenced by this paper.

Metallurgical Thermochemistry." (Pergamon: London 1959

Kubaschewski, E.L.I. Evans
  • Trans. Faraday Soc.,
  • 1957