• DOI:10.1002/(SICI)1521-4095(199801)10:2<93::AID-ADMA93>3.0.CO;2-F
• Corpus ID: 7147581

THE CHEMISTRY OF CONDUCTING POLYTHIOPHENES

@article{Mccullough1998THECO,
  title={THE CHEMISTRY OF CONDUCTING POLYTHIOPHENES},
  author={Richard D Mccullough},
  journal={Advanced Materials},
  year={1998},
  volume={10},
  pages={93-116}
}

• R. D. Mccullough
• Published 1998
• Materials Science
• Advanced Materials

In the late 1970s, conjugated polymers were proclaimed as futuristic new materials that would lead to the next generation of electronic and optical devices. It now appears with the discoveries of, for example, polymer light-emitting diodes (LEDs) and organic transistors that new technologies are imminent. Polythiophenes are an important representative class of conjugated polymers that form some of the most environmentally and thermally stable materials that can be used as electrical conductors, nonlinear optical devices, polymer LEDs, electrochromic or smart windows, photoresists, antistatic coatings, sensors, batteries, electromagnetic shielding materials, artificial noses and muscles, solar cells, electrodes, microwave absorbing materials, new types of memory devices, nanoswitches, optical modulators and valves, imaging materials, polymer electronic interconnects, nanoelectronic and optical devices, and transistors. Polythiophene and its derivatives work very well in some of the above applications and less impressively in other devices. Creative new design and development strategies of new polythiophenes has led to interesting new materials and enhanced performance in certain devices. The ability of molecular designers to begin to understand how to gain control over the structure, properties, and function in polythiophenes continues to make the synthesis of polythiophenes a critical subject in the development of new advanced materials. Here I attempt to review comprehensively the synthesis of polythiophenes. Owing to the enormous literature on this subject, some excellent work in this area will almost certainly have been inadvertently overlooked. However, I will highlight both the pioneering work and the frontiers in the synthesis of polythiophenes. It is important to realize that, as it has become clear that structure plays a dominant role in determining the physical properties of conducting polymers, more research has focused on directing the structure and function of these materials with synthesis. Synthesis can help to determine the magnitude of p overlap along the backbone and eliminate structural defects. Materials assembly (and/or processing) determines interchain overlap and dimensionality. Planarization of the backbone and assembly of the backbone in the form of p stacks lead to better materials and enhanced device performance in almost every category, ranging from electrical conductivity to stability. Therefore, both remarkable enhancements in the electronic and photonic properties of the resultant materials and the creation of new functions, such as new sensory materials, critically depends on the synthesis of the polythiophene. This of course leads to the exciting prospect that the properties of polythiophenes can be selectively engineered through synthesis and assembly. A large portion of both the pioneering and future work in conjugated polymers strongly depends on synthetic chemists creating new polymers that can be fabricated into new devices and whose physics and chemistry can be understood in detail.